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Regulating Surface Reaction Kinetics through Ligand Field Effects for Fast and Reversible Aqueous Zinc Batteries
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-09-09 , DOI: 10.1002/anie.202212780
Bo Liu 1 , Cong Wei 1 , Zixuan Zhu 1 , Yanyan Fang 1 , Zenan Bian 1 , Xin Lei 1 , Ya Zhou 1 , Chongyang Tang 1 , Yitai Qian 1 , Gongming Wang 1
Affiliation  

The boron acid additive can alleviate the intrinsic tradeoff between Zn nucleation/dissolution kinetics and the interfacial hydrogen evolution reaction by modulating the solvation sheath. The formed solvation structure with moderate ligand field strength enables fast and highly reversible Zn deposition.

中文翻译:

通过配体场效应调节快速和可逆水系锌电池的表面反应动力学

硼酸添加剂可以通过调节溶剂化鞘来缓解 Zn 成核/溶解动力学与界面析氢反应之间的内在权衡。形成的具有中等配体场强度的溶剂化结构能够实现快速和高度可逆的锌沉积。
更新日期:2022-09-09
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