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Unraveling the Complex Chirality Evolution in DNA-Assembled High-Order, Hybrid Chiroplasmonic Superstructures from Multi-Scale Chirality Mechanisms
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-09-09 , DOI: 10.1002/anie.202210730
Yongqing Yuan 1 , Huacheng Li 1 , Hao Yang 1 , Cong Han 1 , Huatian Hu 2 , Alexander O Govorov 3 , Hao Yan 4 , Xiang Lan 1
Affiliation  

Multi-scale chirality evolution was observed from DNA-assembled hybrid chiroplasmonic superstructures comprised of metal nanoparticles and organic chromophores, as a result of distinct fundamental chiral interactions at different hierarchical levels. The findings present new challenges to current theoretical frameworks to describe chiral hybrid systems, and will motivate computational and theoretical advances.

中文翻译:

从多尺度手性机制揭示 DNA 组装的高阶混合手性手性超结构的复杂手性演化

从由金属纳米粒子和有机发色团组成的 DNA 组装的杂化手性超结构中观察到多尺度手性演变,这是不同层次水平上不同的基本手性相互作用的结果。这些发现对当前描述手性混合系统的理论框架提出了新的挑战,并将推动计算和理论的进步。
更新日期:2022-09-09
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