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Modulating Supramolecular Charge-Transfer Interactions in the Solid State using Compressible Macrocyclic Hosts
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-09-08 , DOI: 10.1002/anie.202210579
Jia-Rui Wu 1, 2 , Dongxia Li 1 , Gengxin Wu 1 , Meng-Hao Li 1 , Ying-Wei Yang 1
Affiliation  

A cavity compressing strategy is proposed to modulate the macrocyclic host–guest charge-transfer (CT) interactions. The solid-state CT affinities of perethylated leaning pillar[6]arene toward various electron-deficient planar guests could be significantly enhanced by transforming the macrocyclic backbone from the original para-bridged mode into a hybrid para- and meta-bridged isomeric form.

中文翻译:

使用可压缩大环主体调节固态中的超分子电荷转移相互作用

提出了一种腔压缩策略来调节大环主客体电荷转移 (CT) 相互作用。通过将大环骨架从原始对位桥接模式转变为混合对位位桥接异构体形式,可以显着增强全乙基化倾斜柱[6]芳烃对各种缺电子平面客体的固态 CT 亲和力。
更新日期:2022-09-08
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