当前位置: X-MOL 学术Int. J. Appl. Ceram. Technol. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Enhanced thermal conductivity and flexural strength of sintered reaction-bonded silicon nitride with addition of (Y0.96Eu0.04)2O3
International Journal of Applied Ceramic Technology ( IF 2.1 ) Pub Date : 2022-09-03 , DOI: 10.1111/ijac.14192
Shishuai Li 1, 2 , Yongfeng Xia 1 , Dongxu Yao 1 , Hanqin Liang 1 , Yu‐Ping Zeng 1
Affiliation  

Sintered reaction-bonded silicon nitride (SRBSN) with high thermal conductivity was obtained using (Y0.96Eu0.04)2O3 and MgO as sintering additives. Green compacts were nitrided at 1400°C for 4 h. Post-sintering was carried out at 1850 and 1900°C for 4 h, respectively. In reaction-bonded silicon nitride (RBSN) doped with Y2O3 and MgO, the β-Si3N4 content and nitridation degree were 51.1% and 93.8%, respectively. However, the β-Si3N4 content and nitridation degree were 72.6% and 96.7% in a nitrided compact doped with (Y0.96Eu0.04)2O3 and MgO. After post-sintering, the phase composition, microstructure, mechanical properties, and thermal conductivity were investigated. After sintering at 1900°C for 4 h, the thermal conductivity of SRBSN doped with (Y0.96Eu0.04)2O3 and MgO was increased by 16.5% compared to that of the samples doped with Y2O3 and MgO. The highest hardness of 1639 HV and the good flexural strength of 776.4 MPa were also achieved in the sample doped with 2-mol.% (Y0.96Eu0.04)2O3 and 5-mol.% MgO.

中文翻译:

添加 (Y0.96Eu0.04)2O3 提高烧结反应结合氮化硅的导热性和弯曲强度

使用(Y 0.96 Eu 0.04 ) 2 O 3和MgO作为烧结助剂获得了具有高导热性的烧结反应结合氮化硅(SRBSN) 。生坯在 1400°C 下氮化 4 小时。后烧结分别在 1850 和 1900°C 下进行 4 小时。Y 2 O 3和MgO掺杂反应结合氮化硅(RBSN)中β-Si 3 N 4含量和氮化度分别为51.1%和93.8%。而掺杂(Y 0.96 Eu 0.04 )的氮化压块的β-Si 3 N 4含量和氮化度分别为72.6%和96.7%。2 O 3和MgO。后烧结后,研究了相组成、微观结构、机械性能和导热性。在1900℃下烧结4小时后,与掺杂Y 2 O 3和MgO的样品相比,掺杂(Y 0.96 Eu 0.04 ) 2 O 3和MgO的SRBSN的热导率提高了16.5% 。掺杂2-mol.% (Y 0.96 Eu 0.04 ) 2 O 3和5-mol.% MgO的样品也达到了1639 HV的最高硬度和776.4 MPa的良好弯曲强度。
更新日期:2022-09-03
down
wechat
bug