Ultrasmall Copper Nanoclusters in Zirconium Metal-Organic Frameworks for the Photoreduction of CO2,Angewandte Chemie International Edition

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Ultrasmall Copper Nanoclusters in Zirconium Metal-Organic Frameworks for the Photoreduction of CO2
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-09-02 , DOI: 10.1002/anie.202211848
Shan Dai _{1,

2} , Takashi Kajiwara _{3,

4} , Miyuki Ikeda ₃ , Ignacio Romero-Muñiz ₅ , Gilles Patriarche ₆ , Ana E Platero-Prats _{5,

7,

8} , Alexandre Vimont ₂ , Marco Daturi ₂ , Antoine Tissot ₁ , Qiang Xu _{3,

4,

9} , Christian Serre ₁

Affiliation

Institut des Matériaux Poreux de Paris, Ecole Normale Supérieure, ESPCI Paris, CNRS, PSL University, 75005, Paris, France.
Normandie Univ., ENSICAEN, UNICAEN, CNRS, Laboratoire Catalyse et Spectrochimie, 14000, Caen, France.
AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL), National Institute of Advanced Industrial Science and Technology (AIST), Sakyo-ku, Kyoto, 606-8501, Japan.
Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Sakyo-ku, Kyoto, 606-8501, Japan.
Departamento de Química Inorgánica, Facultad de Ciencias, Universidad Autónomade Madrid, Campus de Cantoblanco, 28049, Madrid, Spain.
Université Paris-Saclay, CNRS, Centre de Nanosciences et de Nanotechnologies, 91120, Palaiseau, France.
Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049, Madrid, Spain.
Instituto de Investigación Avanzada en Ciencias Químicas de la UAM, Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049, Madrid, Spain.
Shenzhen Key Laboratory of Micro/Nano-Porous Functional Materials (SKLPM), Department of Chemistry, and Department of Materials Science and Engineering, Southern University of Science and Technology (SUSTech), Nanshan, Shenzhen, Guangdong 518055, China.

A room-temperature synthetic strategy is reported for incorporation of ultrasmall Cu nanoclusters into a series of robust Zr-metal–organic frameworks. The resultant core–shell composites mediate CO₂ photoreduction selectively and outperform similar composites even with variable Cu spatial distribution.

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