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Effect of Acid–Base Characteristics of Zeolite Catalysts on Oxidative Dehydrogenation of Propane with Carbon Dioxide
Theoretical and Experimental Chemistry ( IF 1 ) Pub Date : 2022-08-25 , DOI: 10.1007/s11237-022-09729-2
A. Yu. Kapran, S. M. Orlyk

The peculiarities of propane dehydrogenation with carbon dioxide over zeolite catalysts of different structural types, in particular, BEA with incorporated Zn, Ga (Ta, Nb) heteroelements have been analyzed. The role of CO2 as an oxidant, the effect of acid–base characteristics on propylene selectivity and yield, the stability of catalyst operation, and the routes of activation of reagents on acid–base sites of the surface are considered.



中文翻译:

沸石催化剂酸碱特性对丙烷二氧化碳氧化脱氢的影响

分析了不同结构类型的沸石催化剂,特别是掺入Zn、Ga(Ta、Nb)异质元素的BEA催化剂上二氧化碳脱氢丙烷的特性。考虑了CO 2作为氧化剂的作用、酸碱特性对丙烯选择性和收率的影响、催化剂操作的稳定性以及试剂在表面酸碱位点上的活化途径。

更新日期:2022-08-25
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