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Liquid-like atoms in dense-packed solid glasses
Nature Materials ( IF 41.2 ) Pub Date : 2022-08-15 , DOI: 10.1038/s41563-022-01327-w
C Chang 1, 2 , H P Zhang 1 , R Zhao 1, 2 , F C Li 1 , P Luo 1 , M Z Li 3 , H Y Bai 1, 2, 4
Affiliation  

Revealing the microscopic structural and dynamic pictures of glasses is a long-standing challenge for scientists1,2. Extensive studies on the structure and relaxation dynamics of glasses have constructed the current classical picture3,4,5: glasses consist of some ‘soft zones’ of loosely bound atoms embedded in a tightly bound atomic matrix. Recent experiments have found an additional fast process in the relaxation spectra6,7,8,9, but the underlying physics of this process remains unclear. Here, combining extensive dynamic experiments and computer simulations, we reveal that this fast relaxation is associated with string-like diffusion of liquid-like atoms, which are inherited from the high-temperature liquids. Even at room temperature, some atoms in dense-packed metallic glasses can diffuse just as easily as they would in liquid states, with an experimentally determined viscosity as low as 107 Pa·s. This finding extends our current microscopic picture of glass solids and might help establish the dynamics–property relationship of glasses4.



中文翻译:

致密固体玻璃中的液态原子

揭示眼镜的微观结构和动态图片是科学家1,2长期面临的挑战。对玻璃结构和弛豫动力学的广泛研究构建了当前的经典图3,4,5:玻璃由嵌入紧密结合的原子矩阵中的松散结合原子的一些“软区”组成。最近的实验在弛豫光谱中发现了一个额外的快速过程6,7,8,9,但这个过程的基本物理学仍不清楚。在这里,结合广泛的动态实验和计算机模拟,我们揭示了这种快速弛豫与液态原子的弦状扩散有关,这些原子继承自高温液体。即使在室温下,密集金属玻璃中的一些原子也可以像液态一样容易扩散,实验确定的粘度低至 10 7  Pa·s。这一发现扩展了我们目前对玻璃固体的微观图景,并可能有助于建立玻璃的动力学特性关系4

更新日期:2022-08-16
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