Russian Journal of Inorganic Chemistry ( IF 2.1 ) Pub Date : 2022-08-09 , DOI: 10.1134/s0036023622100278 M. Kumar , S. Ahmad , A. Ali
Abstract
Transition metal complexes with redox-active ligands is an actively developing field of bioinorganic chemistry. The catalytic transformations encountered by the redox-active ligands with transition metal as the active catalyst in the catalytic mechanism. The understanding of the redox-active nature of the ligands, increasing endeavor are devoted to bring about useful chemical transformations such as oxidation of alkene, water oxidation, bond activation etc. In the past, there are many catalysts have been investigated to transformation of organic species. Thus, in the present review article having target to highlight the redox-active ligands that coordinated to transition metals and perform catalytic activity towards the many organic species with the facts which are citing by some recent research articles.
中文翻译:
氧化还原活性配体框架支持的催化反应性:小型回顾
摘要
具有氧化还原活性配体的过渡金属配合物是生物无机化学的一个活跃发展领域。以过渡金属为活性催化剂的氧化还原配体在催化机理中遇到的催化转化。对配体的氧化还原活性的理解,越来越多的努力致力于带来有用的化学转化,如烯烃的氧化、水氧化、键活化等。过去,已经研究了许多催化剂来转化有机物物种。因此,本综述文章的目标是突出与过渡金属配位的氧化还原活性配体,并对许多有机物种发挥催化活性,这些事实已被最近的一些研究文章引用。