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Investigation of glass forming ability, crystallization behavior, and soft magnetic properties of Fe–B–P–C–Cu alloy ribbons
Intermetallics ( IF 4.4 ) Pub Date : 2022-08-04 , DOI: 10.1016/j.intermet.2022.107675
Yuluo Li , Ningning Shen , Li Chen , Kuang Lv , Xidong Hui

The effect of Cu content on GFA, crystallization behavior, and soft magnetic properties in high P Fe84+xB6P6C3Cu1−x (x = 0, 0.2, 0.4, 0.6, and 1.0 at. %) alloy ribbons were systematically investigated to balance the relationship between glass forming ability (GFA), heat treatment window, and soft magnetic properties of high saturation magnetic flux density (Bs) Fe-based nanocrystalline alloys. It was discovered that lowering Cu promotes the formation of an amorphous structure. The GFA of alloys rises from 23 μm for Fe84B6P6C3Cu1 to 29 μm for Fe84.4B6P6C3Cu0.6. Analysis of thermal physical properties shows that when Cu content is between 1.0 at. % and 0.6 at. %, reducing Cu in the alloys does not affect the onset temperature of the first crystallization peak (Tx1), the second one (Tx2), and ΔTT = Tx2 − Tx1), whereas when Cu content is less than 0.6 at. %, reducing Cu leads to an increase in Tx1 and a decrease in Tx2 and ΔT, which is not conducive to obtaining a wide temperature range of precipitation of a single α-Fe phase. The alloys have a wide range of crystallization annealing temperature (693–753 K) and annealing time (60–6 min) to obtain a low coercivity (Hc) of about 8.0 A/m, high Bs of about 1.80 T, and high effective magnetic permeability (μe) of about 10000 when Cu is between 1.0 at. % and 0.6 at. %. The Bs, Hc, and μe of Fe84.4B6P6C3Cu0.6 alloy annealed at 723 K for 30 min are 1.82 T, 8.1 A/m, and 10820, respectively.



中文翻译:

Fe-B-P-C-Cu合金带的玻璃形成能力、结晶行为和软磁性能研究

Cu含量对高P Fe 84+x B 6 P 6 C 3 Cu 1−x (x = 0, 0.2, 0.4, 0.6, and 1.0 at. %)合金的GFA、结晶行为和软磁性能的影响为了平衡高饱和磁通密度 ( Bs ) 铁基纳米晶合金的玻璃形成能力 (GFA)、热处理窗口和软磁性能之间的关系,系统地研究了碳带。发现降低Cu促进了非晶结构的形成。Fe 84 B 6 P 6 C 3 Cu 1合金的 GFA 从 23 μm 上升Fe 84.4 B 6 P 6 C 3 Cu 0.6为 29 μm 。热物性分析表明,当Cu含量在1.0at之间时。% 和 0.6 在。%,减少合金中的Cu不影响第一个结晶峰(Tx1)、第二个结晶峰( Tx2  ) 和ΔTΔT  =  Tx2 - Tx1 )的起始温度,而当Cu含量为小于 0.6 at。%,减少 Cu 导致T x1增加和T x2和 Δ T减少,这不利于获得单个α-Fe相析出的宽温度范围。该合金具有宽范围的结晶退火温度 (693–753 K) 和退火时间 (60–6 min) 以获得约 8.0 A/m的低矫顽力 ( H c )、约 1.80 T 的高B s和当 Cu 在 1.0 at 之间时,高有效磁导率 ( μ e ) 约为 10000。% 和 0.6 在。%。Fe 84.4 B 6 P 6 C 3 Cu 0.6B sH cμ e在 723 K 退火 30 分钟的合金分别为 1.82 T、8.1 A/m 和 10820。

更新日期:2022-08-05
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