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Ion-pairing assemblies of heteroporphyrin-based π-electronic cation with various counteranions
Chemical Communications ( IF 4.9 ) Pub Date : 2022-08-04 , DOI: 10.1039/d2cc02345h
Masaki Fujita 1 , Yohei Haketa 1 , Hiroki Tanaka 1 , Nobuhiro Yasuda 2 , Hiromitsu Maeda 1
Affiliation  

Various counteranions of the thiaporphyrin–NiII complex as a π-electronic cation were exchanged for preparing stable ion pairs. The ion-pairing assembling modes, which included contributions of charge-by-charge and charge-segregated modes, and properties depended on the geometries and electronic states of the counteranions.

中文翻译:

基于杂卟啉的 π- 电子阳离子与各种抗衡阴离子的离子配对组装

硫卟啉-Ni II配合物作为 π 电子阳离子的各种抗衡阴离子被交换以制备稳定的离子对。离子对组装模式,包括逐电荷和电荷分离模式的贡献,其性质取决于反阴离子的几何形状和电子状态。
更新日期:2022-08-04
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