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Study on preparation of Nb3Sn films by bronze route
Physica C: Superconductivity and its Applications ( IF 1.7 ) Pub Date : 2022-07-29 , DOI: 10.1016/j.physc.2022.1354113
Liang Zhu , Xiangyang Lu , Ziqin Yang , Weiwei Tan , Yujia Yang , Li Xiao , Datao Xie

As a promising material, in the field of superconducting radio frequency (SRF), Nb3Sn could be prepared via bronze route, which is fairly mature for preparing the superconducting cable. This paper studies how different annealing temperature and time affect the superconducting properties of Nb3Sn films made by bronze route. Niobium films with μm thickness were deposited on bronze substrates by magnetron sputtering. The prepared samples were annealed at 700 °C and 750 °C for several hours to allow the diffusion of Sn from the bronze substrate to the niobium layer and the formation of the Nb3Sn phase. The obtained films have been characterized via X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy analysis (EDS), and magnetic property measurement system (MPMS). The peaks of the Nb3Sn phase were found by XRD and the EDS result showed the Sn% of the cross-section fluctuates around 23at.%. The average crystallite size is estimated to be about 82 nm. The highest critical temperature of Nb3Sn films prepared by this method is up to 17.6 K.



中文翻译:

青铜法制备Nb3Sn薄膜的研究

作为一种很有前途的材料,在超导射频(SRF)领域,Nb 3 Sn 可以通过青铜路线制备,在制备超导电缆方面已经相当成熟。本文研究了不同退火温度和时间对青铜路线制备的Nb 3 Sn薄膜超导性能的影响。通过磁控溅射将厚度为 μm 的铌薄膜沉积在青铜基板上。制备的样品在 700°C 和 750°C 下退火几个小时,以使 Sn 从青铜基底扩散到铌层并形成 Nb 3锡相。通过X射线衍射(XRD)、扫描电子显微镜(SEM)、能量色散X射线光谱分析(EDS)和磁性能测量系统(MPMS)对所得薄膜进行了表征。XRD发现Nb 3 Sn相的峰,EDS结果显示横截面的Sn%在23at.%左右波动。平均微晶尺寸估计为约 82 nm。该方法制备的Nb 3 Sn薄膜的最高临界温度可达17.6 K。

更新日期:2022-08-02
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