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Microstructure and Corrosion Behavior of MAO-SG Composite Coating on 7075 Aluminum Alloy
Transactions of the Indian Institute of Metals ( IF 1.6 ) Pub Date : 2022-07-14 , DOI: 10.1007/s12666-022-02673-8
X. W. Chen, L. P. Cai, D. F. Zhang, M. L. Li, Y. Ran, W. Ping

To improve the corrosion resistance of 7075 aluminum alloy microarc oxidation (MAO) coating, graphene of 3 g/L was adsorbed and deposited in the coating. Then, the microarc oxidation–sol–gel (MAO-SG) composite coating was obtained by sealing the micropores of the coating with TiO2 sol–gel. Electrochemical tests of 7075 aluminum alloy matrix, undoped sample, doped graphene sample and sealed sample were carried out in 3.5wt.% NaCl solution. The results show that compared with the blank sample, the self-corrosion potential of the sealed sample is increased by 98.1%, and the self-corrosion current density is reduced by 4 orders of magnitude. After immersion corrosion for 720 h, the corrosion rate of MAO-SG composite coating is 3.4 × 10–5 mm/a, and its corrosion resistance is still better than that of single MAO coating. This is due to the strong conductivity of graphene and the blocking effect of TiO2 sol–gel.



中文翻译:

7075铝合金MAO-SG复合涂层的显微组织和腐蚀行为

为提高7075铝合金微弧氧化(MAO)涂层的耐腐蚀性,涂层中吸附沉积了3 g/L的石墨烯。然后,通过用TiO 2溶胶-凝胶封闭涂层的微孔,获得微弧氧化-溶胶-凝胶(MAO-SG)复合涂层。7075铝合金基体、未掺杂样品、掺杂石墨烯样品和密封样品在3.5wt.% NaCl溶液中进行电化学测试。结果表明,与空白样品相比,密封样品的自腐蚀电位提高了98.1%,自腐蚀电流密度降低了4个数量级。浸泡腐蚀720 h后,MAO-SG复合涂层的腐蚀速率为3.4×10 –5 mm/a,其耐腐蚀性仍优于单层 MAO 涂层。这是由于石墨烯的强导电性和 TiO 2溶胶-凝胶的阻挡作用。

更新日期:2022-07-14
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