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Ion-imprinted antifouling nanocomposite membrane for separation of lithium ion
Korean Journal of Chemical Engineering ( IF 2.7 ) Pub Date : 2022-07-06 , DOI: 10.1007/s11814-022-1176-2
Dongshu Sun , Tianyu Zhou , Yang Lu , Yongsheng Yan , Chunbo Liu , Guangbo Che

Membrane fouling is a primary challenge restricting the practical application of membrane separation technology. Inspired by the idea that improving hydrophilicity would lead to antifouling performance of membrane material. In this work, ion-imprinted antifouling nanocomposite membrane (LiI-NcMs) blended with GO and TiO2 nanomaterial was fabricated for selective separation of lithium ion. As a result, markedly improved hydrophilicity was achieved on LiI-NcMs (55.1° for contact angle). LiI-NcMs also showed good selective adsorption capacity in the mixed solution of Mg2+ and Li+. Moreover, LiI-NcMs exhibited superior stability; after 20 adsorption/desorption cycles a maximum adsorption capacity of 88.1% can be maintained. This work demonstrates a new and facile approach to prepare novel membrane separation material for a particular substance for efficient selective separation in industrial applications.



中文翻译:

用于分离锂离子的离子印迹防污纳米复合膜

膜污染是限制膜分离技术实际应用的主要挑战。受到提高亲水性将导致膜材料防污性能的想法的启发。在这项工作中,制备了与GO和TiO 2纳米材料混合的离子印迹防污纳米复合膜(LiI-NcMs),用于选择性分离锂离子。结果,在 LiI-NcMs 上实现了显着改善的亲水性(接触角为 55.1°)。LiI-NcMs在Mg 2+和Li +的混合溶液中也表现出良好的选择性吸附能力. 此外,LiI-NcMs 表现出优异的稳定性;在 20 次吸附/解吸循环后,可保持 88.1% 的最大吸附容量。这项工作展示了一种新的简便方法,可以为特定物质制备新型膜分离材料,以在工业应用中进行有效的选择性分离。

更新日期:2022-07-07
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