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Effect of hot-working process on interface structure and ductile-to-brittle transition temperature of tungsten alloy reinforced by Al2O3 particles
International Journal of Refractory Metals & Hard Materials ( IF 3.6 ) Pub Date : 2022-07-03 , DOI: 10.1016/j.ijrmhm.2022.105945
Changji Wang , Xiaonan Dong , Shizhong Wei , Hua Yu , Kunming Pan , Chong Chen , Mei Xiong , Feng Mao , Hailin Cui , Liqiang Xiao , Zhili Dong , Shu Wang

The W-0.25 wt%Al2O3 alloy was fabricated by a powder metallurgy processing route, including hydrogen reduction, induction sintering and hot swaging. Al2O3 particles are absorbed on the surface of W particles with size ranging from 50 to 1000 nm. The microstructure of sintered alloy presents equiaxed grains with an average size of 8.6 μm and TEM result shows that a semi-coherent relationship exists in between W and Al2O3. After swaging, the swaged W-0.25 wt%Al2O3 alloy with fully dense was obtained. EBSD result indicates most of grains are obviously elongated and the average aspect ratio of W grains is 2.3:1. There is an obvious transition layer with a thickness of approximately 20 nm between W and Al2O3. The interface displays an amorphous feature because of uncoordinated deformation occurred in swaging process. 3-point bend tests show that the ductile-to-brittle transition temperature of sintered alloy is in the range of 350–400 °C. Moreover, the swaged alloy begins to exhibit obvious ductile behavior at 100–200 °C and the bending strength increases with increasing temperature, which reaches a maximum value of 1762 MPa at 400 °C.



中文翻译:

热加工工艺对Al2O3颗粒增强钨合金界面结构和韧脆转变温度的影响

W-0.25 wt%Al 2 O 3合金采用粉末冶金工艺路线制备,包括氢还原、感应烧结和热锻造。Al 2 O 3颗粒吸附在W颗粒表面,粒径范围为50~1000 nm。烧结合金显微组织呈等轴晶粒,平均粒径为8.6 μm,TEM结果表明W与Al 2 O 3之间存在半共格关系。型锻后,型锻 W-0.25 wt%Al 2 O 3得到完全致密的合金。EBSD结果表明大部分晶粒明显拉长,W晶粒的平均纵横比为2.3:1。W和Al 2 O 3之间有一个明显的过渡层,厚度约为20 nm 。由于型锻过程中发生不协调的变形,界面呈现出无定形特征。三点弯曲试验表明,烧结合金的韧脆转变温度在 350-400 ℃范围内。此外,型锻合金在 100~200 ℃开始表现出明显的延展性,弯曲强度随温度升高而增加,在 400 ℃时达到最大值 1762 MPa。

更新日期:2022-07-04
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