An Fe(OTf)₂-catalyzed three-component coupling reaction of α,β,γ,δ-unsaturated carbonyl compounds with alkylsilyl peroxides in the presence of certain heteronucleophiles (ROH and indole) is realized under mild reaction conditions. A variety of α,β,γ,δ-diene carbonyl substrates with different substituents were successfully employable via combination with several different alkylsilyl peroxides. This new approach is also applicable to the double functionalization of diene substrates.

中文翻译：

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Fe催化的α,β,γ,δ-不饱和羰基化合物和共轭二烯与过氧化物和亲核试剂的三组分偶联反应

在温和的反应条件下，在某些异亲核试剂（ROH 和吲哚）存在下，实现了 Fe(OTf) ₂催化的 α,β,γ,δ-不饱和羰基化合物与过氧化烷基甲硅烷的三组分偶联反应。通过与几种不同的烷基甲硅烷基过氧化物组合，可以成功地使用具有不同取代基的各种α，β，γ，δ-二烯羰基底物。这种新方法也适用于二烯底物的双功能化。