Herein, a practical and highly efficient method for visible-light-induced copper-catalyzed N-aminoquinoline-directed asymmetric C(sp³)–C(sp³)–H glycosylation was reported. At the same time, C(sp³)–C(sp³)–H glycosylation of nondeoxysugars with amino acids to construct C-glycopeptides was achieved. This approach promoted the synthesis of various C-glycopeptides and provided a new model for the synthesis of C-glycoamino acids.

中文翻译：

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可见光诱导的铜催化不对称 C(sp3)–C(sp3)–H 糖基化：获得 C-糖肽

本文报道了一种实用且高效的可见光诱导铜催化N-氨基喹啉定向不对称 C(sp ³ )-C(sp ³ )-H 糖基化方法。同时，实现了非脱氧糖与氨基酸的C(sp ³ )-C(sp ^{3 )-H糖基化构建C-糖肽。}该方法促进了多种C-糖肽的合成，为C-糖氨基酸的合成提供了新的模型。