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Optical Duality of Molybdenum Disulfide: Metal and Semiconductor
Nano Letters ( IF 10.8 ) Pub Date : 2022-06-21 , DOI: 10.1021/acs.nanolett.2c00853
Wonkil Sakong , Hamza Zad Gul 1 , Byungwook Ahn , Suar Oh , Giheon Kim , Eunji Sim 2 , Jaeuk Bahng 2 , Hojoon Yi , Minjeong Kim , Minhee Yun 3 , Seong Chu Lim 2
Affiliation  

The two different light–matter interactions between visible and infrared light are not switchable because control mechanisms have not been elucidated so far, which restricts the effective spectral range in light-sensing devices. In this study, modulation of the effective spectral range is demonstrated using the metal–insulator transition of MoS2. Nondegenerate MoS2 exhibits a photoconductive effect in detecting visible light. In contrast, degenerate MoS2 responds only to mid-infrared (not visible) light by displaying a photoinduced heating effect via free carrier absorption. Depending on the doping level, the optical behavior of MoS2 simulates the photoconductivity of either the semiconductor or the metal, further indicating that the optical metal–insulator transition is coherent with its electrical counterpart. The electrical switchability of MoS2 enables the development of an unprecedented and novel design optical sensor that can detect both visible and mid-IR (wavelength of 9.6 μm) ranges with a singular optoelectronic device.

中文翻译:

二硫化钼的光学二元性:金属和半导体

可见光和红外光之间的两种不同的光-物质相互作用是不可切换的,因为迄今为止尚未阐明控制机制,这限制了光传感设备的有效光谱范围。在这项研究中,使用 MoS 2的金属-绝缘体跃迁证明了有效光谱范围的调制。非简并MoS 2在检测可见光时表现出光电导效应。相比之下,简并的 MoS 2仅对中红外(不可见)光作出响应,通过自由载流子吸收显示光致加热效应。根据掺杂水平,MoS 2的光学行为模拟了半导体或金属的光电导率,进一步表明光学金属 - 绝缘体转变与其电对应物是相干的。MoS 2的电可切换性使开发前所未有的新颖设计光学传感器成为可能,该传感器可以通过单个光电器件检测可见光和中红外(波长为 9.6 μm)范围。
更新日期:2022-06-21
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