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Reactivity in Nickel-Catalyzed Multi-component Sequential Reductive Cross-Coupling Reactions
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-06-21 , DOI: 10.1002/anie.202204144
Haifeng Chen 1 , Huifeng Yue 1 , Chen Zhu 1 , Magnus Rueping 1
Affiliation  

The nickel-catalyzed three-component reductive carbonylation of alkyl halides, aryl halides, and ethyl chloroformate is described. The use of ethyl chloroformate as a safe and readily available source of CO provides an efficient and practical alternative for the synthesis of aryl-alkyl ketones.

中文翻译:

镍催化多组分顺序还原交叉偶联反应中的反应性

描述了烷基卤化物、芳基卤化物和氯甲酸乙酯的镍催化三组分还原羰基化。使用氯甲酸乙酯作为一种安全且容易获得的 CO 来源,为芳基烷基酮的合成提供了一种有效且实用的替代方案。
更新日期:2022-06-21
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