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Experimental and theoretical investigations of lithium isotopes separation using 10-hydroxybenzoquinoline
Journal of Radioanalytical and Nuclear Chemistry ( IF 1.6 ) Pub Date : 2022-06-19 , DOI: 10.1007/s10967-022-08378-y
Zhanqin Wang , Yongzhong Jia , Bing Liu , MiXiang Qi , Yan Jing , Ying Yao

Effective separation of lithium isotopes (6Li and 7Li) is a significant challenge in developing clean nuclear energy. In this work, 7Li was separated and enriched by 10-hydroxybenzoquinoline using flotation complexation extraction under alkaline conditions. In addition, the thermodynamic process of lithium isotope separation was discussed and the separation mechanism was explained by theoretical calculation according to density functional theory. Finally, the conditions of the Li+ stripping process were investigated. The results showed that the single-stage separation factor was 1.023 ± 0.001, and the abundance of 7Li reached 92.72%. The stripping ratio of lithium reached 98% by stripping five times using pure water.



中文翻译:

10-羟基苯并喹啉分离锂同位素的实验和理论研究

锂同位素(6 Li和7 Li)的有效分离是开发清洁核能的重大挑战。在这项工作中,在碱性条件下采用浮选络合萃取 10-羟基苯并喹啉对7 Li 进行了分离和富集。此外,还讨论了锂同位素分离的热力学过程,并根据密度泛函理论通过理论计算解释了分离机理。最后,研究了锂离子剥离工艺的条件。结果表明,单级分离因子为1.023±0.001,丰度为7李达92.72%。使用纯水进行5次反萃取,锂的反萃取率达到98%。

更新日期:2022-06-20
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