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Discrete palladium clusters that consist of two mutually bisecting perpendicular planes
Chemical Science ( IF 8.4 ) Pub Date : 2022-06-15 , DOI: 10.1039/d2sc02302d Naoya Kojima 1 , Misaki Kato 1 , Yusuke Sunada 1, 2
Chemical Science ( IF 8.4 ) Pub Date : 2022-06-15 , DOI: 10.1039/d2sc02302d Naoya Kojima 1 , Misaki Kato 1 , Yusuke Sunada 1, 2
Affiliation
The construction of novel molecules with unprecedented alignments of the constituent elements has revolutionized the field of functional materials. The arrangement of two or more planar subunits in a mutually perpendicular fashion is a frequently encountered approach to produce novel functional materials. Previous examples of such materials can be categorized into two well-investigated families: spiro-conjugated and dumbbell-shaped structures, wherein the two planes are aligned orthogonally via a single atom or an axis, respectively. This article describes a third family: reaction of [Pd(CNtBu)2]3 with Sn3Me8 or Ge6Me12 afforded a Pd7Sn4 cluster and a Pd8Ge6 cluster that consist of two mutually bisecting perpendicular planes. In the Pd7Sn4 cluster, the two equivalent Pd5Sn2 planes share three palladium atoms that include a dihedral angle of 85.6°.
中文翻译:
由两个相互平分的垂直平面组成的离散钯簇
具有前所未有的组成元素排列的新型分子的构建已经彻底改变了功能材料领域。以相互垂直的方式排列两个或多个平面亚基是生产新型功能材料的常见方法。此类材料的先前示例可分为两个经过充分研究的家族:螺共轭结构和哑铃形结构,其中两个平面分别通过单个原子或轴正交排列。本文描述了第三个家族:[Pd(CN t Bu) 2 ] 3与 Sn 3 Me 8或 Ge 6 Me的反应图12提供了由两个相互平分的垂直平面组成的Pd 7 Sn 4簇和Pd 8 Ge 6簇。在 Pd 7 Sn 4簇中,两个等效的 Pd 5 Sn 2平面共享三个钯原子,其二面角为 85.6°。
更新日期:2022-06-15
中文翻译:
由两个相互平分的垂直平面组成的离散钯簇
具有前所未有的组成元素排列的新型分子的构建已经彻底改变了功能材料领域。以相互垂直的方式排列两个或多个平面亚基是生产新型功能材料的常见方法。此类材料的先前示例可分为两个经过充分研究的家族:螺共轭结构和哑铃形结构,其中两个平面分别通过单个原子或轴正交排列。本文描述了第三个家族:[Pd(CN t Bu) 2 ] 3与 Sn 3 Me 8或 Ge 6 Me的反应图12提供了由两个相互平分的垂直平面组成的Pd 7 Sn 4簇和Pd 8 Ge 6簇。在 Pd 7 Sn 4簇中,两个等效的 Pd 5 Sn 2平面共享三个钯原子,其二面角为 85.6°。