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Recent advances in MOFs/MOF derived nanomaterials toward high-efficiency aqueous zinc ion batteries
Coordination Chemistry Reviews ( IF 20.6 ) Pub Date : 2022-06-08 , DOI: 10.1016/j.ccr.2022.214642
Tianji Zhao, Haoyang Wu, Xinhai Wen, Jie Zhang, Haibo Tang, Yijie Deng, Shijun Liao, Xinlong Tian

Aqueous zinc ion batteries (AZIBs) with cost-effectiveness, intrinsic safety, environmental benignity, easy manufacturing and high specific and volumetric capacity are considered one of alternatives with the best prospects for next-generation secondary batteries. However, current AZIBs are still difficult to meet large-scale commercial applications, constrained by major challenges from the cathode, electrolyte and zinc anode. Recently, due to the flourishing porous structure, abundant active sites, and versatile functionalization, metal–organic framework (MOF)/MOF-derived nanomaterials have been extensively investigated in AZIBs, and many significant developments have been witnessed. In this review, the components and energy storage mechanisms of AZIBs are firstly presented. Moreover, recent developments in MOF/MOF-derived nanomaterials in AZIBs are summarized in detail, and the relationship between the structure and composites of MOF/MOF-derived nanomaterials and the electrochemical performance of AZIBs is highlighted. Finally, the research directions and perspectives of MOFs/MOF-derived nanomaterials for advanced AZIBs are proposed. This review will provide instructive guidance for the rational design of MOFs or MOF-derived nanomaterials in AZIBs.



中文翻译:

MOFs/MOF衍生纳米材料在高效水系锌离子电池方面的最新进展

水系锌离子电池(AZIBs)具有成本效益、本质安全、环境友好、易于制造、高比容量和高容量等优点,被认为是下一代二次电池最具前景的替代品之一。然而,目前的AZIBs仍然难以满足大规模商业应用,受到阴极、电解质和锌阳极的重大挑战的限制。近年来,由于金属有机框架(MOF)/MOF衍生的纳米材料具有丰富的多孔结构、丰富的活性位点和多功能的功能化,在AZIBs中得到了广泛的研究,并见证了许多重大进展。在这篇综述中,首先介绍了AZIBs的组件和储能机制。而且,详细总结了AZIBs中MOF/MOF衍生纳米材料的最新进展,重点介绍了MOF/MOF衍生纳米材料的结构和复合材料与AZIBs电化学性能的关系。最后,提出了用于先进AZIBs的MOFs/MOF衍生纳米材料的研究方向和展望。本综述将为 AZIBs 中 MOF 或 MOF 衍生纳米材料的合理设计提供指导。

更新日期:2022-06-08
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