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Synthesis and mechanical and thermal properties of multiblock terpoly(ester-ether-amide) thermoplastic elastomers with variable mole ratio of ether and amide block
Polish Journal of Chemical Technology ( IF 1 ) Pub Date : 2021-12-01 , DOI: 10.2478/pjct-2021-0032
Beata Schmidt 1 , Joanna Rokicka 1
Affiliation  

Abstract A series of the terpolymers of poly[(trimethylene terephthalate)-block-(oxytetramethylene)-block-laurolactam] with a variable molar ratio of ether and amide block and constant molecular weights of PA12 = 2000 g/mole and PTMO = 1000 g/mole have been obtained. The influence of changes of these molar ratios on the functional properties and the values of phase change temperatures of the products have been determined. The thermal properties and the phase separation of obtained systems were defined by DSC, DMTA and WAXS methods. The chemical structure of obtained materials was studied by FT-IR and 13C NMR methods. The mechanical and elastic properties of these polymers were evaluated.

中文翻译:

可变醚和酰胺嵌段摩尔比的多嵌段三聚(酯-醚-酰胺)热塑性弹性体的合成及力学和热性能

摘要 一系列聚[(对苯二甲酸丙二醇酯)-嵌段-(氧四亚甲基)-嵌段-月桂内酰胺]的三元共聚物,具有可变的醚和酰胺嵌段摩尔比,PA12 = 2000 g/mole和PTMO = 1000 g的恒定分子量/摩尔已获得。已经确定了这些摩尔比的变化对产品的功能特性和相变温度值的影响。所得体系的热性能和相分离通过 DSC、DMTA 和 WAXS 方法确定。通过FT-IR和13C NMR方法研究了所得材料的化学结构。评估了这些聚合物的机械和弹性性能。
更新日期:2021-12-01
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