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Ruthenium-Catalyzed Decarboxylative Rearrangement of 4-Alkenyl-isoxazol-5-ones to Pyrrole Derivatives
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2022-06-05 , DOI: 10.1002/ejoc.202200496
Letizia Molteni 1 , Camilla Loro 2 , Michael S. Christodoulou 3 , Marta Papis 4 , Francesca Foschi 4 , Egle M. Beccalli 1 , Gianluigi Broggini 5
Affiliation  

Easily accessible isoxazol-5(4H)-ones are useful precursors of different heterocycles. In this work, the ruthenium-catalyzed transformation of 4-alkenyl-substituted isoxazol-5-ones to 1H-pyrrole derivatives is reported.

中文翻译:

钌催化4-烯基-异恶唑-5-酮脱羧重排生成吡咯衍生物

容易获得的异恶唑-5(4 H )-酮是不同杂环的有用前体。在这项工作中,报道了钌催化的 4-烯基取代的异恶唑-5-酮向 1 H-吡咯衍生物的转化。
更新日期:2022-06-05
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