To enhance the conductivity of sulfonated polyether ether ketone (SPEEK, SP) membrane and avoid the loss of ionic liquid (IL), using aminopropyloligosisiloxane (NH₂-POSS) as molecular hybrid filler, a self-assembled medium temperature and non-humidified SP/IL/NH₂-POSS hybrid membrane was prepared. NH₂-POSS can be assembled into the hydrophilic domain ion phase of SPEEK. In which, –NH₂ of NH₂-POSS and –SO₃H of SPEEK formed acid-base pairs at the interface which were conducive to the construction of proton transport channel. In addition, NH₂-POSS enriched IL in the hydrophilic domain, which retained IL while synergistically increased the conductivity. The results showed that the IL loss rate of SP/IL/NH₂-POSS-2 membrane was 46.9 wt%, which was about 55.8% of SP/IL membrane; the conductivity of SP/IL/NH₂-POSS-2 membrane at 200 °C without humidification was 5.51 mS·cm⁻¹, which was about 4 times that of SP/IL membrane.

为提高磺化聚醚醚酮（SPEEK，SP）膜的电导率，避免离子液体（IL）的损失，以氨基丙基低聚硅氧烷（NH ₂ -POSS）为分子杂化填料，自组装中温非加湿SP制备了/IL/NH ₂ -POSS杂化膜。NH ₂ -POSS 可以组装到SPEEK 的亲水域离子相中。其中，NH ₂ -POSS的-NH _{2和SPEEK的-SO 3} H在界面处形成酸碱对，有利于质子传输通道的构建。此外，NH ₂-POSS在亲水结构域中富集了IL，它保留了IL，同时协同增加了电导率。结果表明，SP/IL/NH ₂ -POSS-2膜的IL损失率为46.9 wt%，约为SP/IL膜的55.8%；SP/IL/NH ₂ -POSS-2膜在200℃不加湿时的电导率为5.51 mS·cm ^-1，约为SP/IL膜的4倍。