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Circularly polarized perovskite luminescence with dissymmetry factor up to 1.9 by soft helix bilayer device
Matter ( IF 18.9 ) Pub Date : 2022-05-31 , DOI: 10.1016/j.matt.2022.05.012
Shuaijun Liu , Xuan Liu , Yongzhen Wu , Diwei Zhang , Yue Wu , He Tian , Zhigang Zheng , Wei-Hong Zhu

Metal halide perovskites are exceptional light-emitting materials. Endowing perovskites with circularly polarized luminescence (CPL) offers great promise for innovative applications, but the existing strategies are inefficient in acquiring large dissymmetry factor (glum), high quantum efficiency, and long-term stability. Here, we demonstrate bright and stable CPL with a glum value up to 1.9 from perovskites in chiral liquid crystal (LC)-based soft helix devices featuring a bilayer architecture. The incorporation of an optimized polymer of polyacrylonitrile (PAN) in the bilayer device remarkably improves luminescent efficiency and stability of perovskite, while perfectly preserving optical and stimuli-responsive characteristics of chiral LCs. The resulting bilayer devices allow systematical composition engineering of both perovskite and soft helix and enable full-color CPL with high glum values. Moreover, CPL-active devices with diverse graphical patterns and reversible thermal-switching behavior can further expand the scaffold for cryptology and anti-counterfeiting applications.



中文翻译:

软螺旋双层器件实现不对称因子高达 1.9 的圆偏振钙钛矿发光

金属卤化物钙钛矿是一种特殊的发光材料。赋予钙钛矿以圆偏振发光(CPL)为创新应用提供了巨大的希望,但现有的策略在获得大的不对称因子(g lum)、高量子效率和长期稳定性方面效率低下。在这里,我们展示了明亮且稳定的 CPL 与g lum在具有双层结构的基于手性液晶 (LC) 的软螺旋器件中,钙钛矿的值高达 1.9。在双层器件中加入优化的聚丙烯腈 (PAN) 聚合物显着提高了钙钛矿的发光效率和稳定性,同时完美地保留了手性 LC 的光学和刺激响应特性。由此产生的双层器件允许钙钛矿和软螺旋的系统组合工程,并实现具有高亮度值的全彩色 CPL 此外,具有多种图形模式和可逆热切换行为的 CPL 有源器件可以进一步扩展用于密码学和防伪应用的支架。

更新日期:2022-05-31
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