The ability of copper(II) complexes with 4-phenylthiosemicarbazide and amino acid anions to act as initiators of polymerization of methyl methacrylate and styrene is shown. It was found that the activation energies of polymerization and initiation in the presence of copper(II) complexes are significantly reduced in comparison with the process of thermal initiation. It is established that polymerization of methyl methacrylate initiated by the studied complexes resulted in the formation of syndiotactic polymer.

中文翻译：

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甘氨酰甘氨酸铜 (II) 和氨基乙酸络合物与 4-苯基氨基硫脲引发乙烯基单体的聚合

显示了铜 (II) 与 4-苯基氨基硫脲和氨基酸阴离子的络合物作为甲基丙烯酸甲酯和苯乙烯聚合引发剂的能力。发现与热引发过程相比，在铜（II）配合物存在下聚合和引发的活化能显着降低。已确定由所研究的配合物引发的甲基丙烯酸甲酯聚合导致间规聚合物的形成。