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Interlayer-spacing-regulated MXene/rGO Foam for Multi-functional Zinc-ion Microcapacitors
Energy Storage Materials ( IF 20.4 ) Pub Date : 2022-05-27 , DOI: 10.1016/j.ensm.2022.05.033
Hongyun Zhang , Zhichao Wei , Jinghang Wu , Feng Cheng , Yanan Ma , Weijie Liu , Yongfa Cheng , Yangjian Lin , Nishuang Liu , Yihua Gao , Yang Yue

The traditional 3D porous structures often sacrifice density for high porosity, which is not conducive for energy storage under a limited space. So, it is a challenge to seek the strategy to well balance of the density and porosity in foam materials. In this work, we fabricated MXene based foam by the hydrazine vapor-induced reduction, which can achieve the precise regulation on the density (100–360 mg cm−3) and pore size (5.08–61.04 μm) while maintaining its high porosity over 77.9%. And it is carried out by simply tuning the oxygenated functional group concentration of the original MXene/GO films. Then the interlayer-spacing-regulated 3D MXene/rGO foams was used to construct the multifunctional Zinc ion microcapacitor (ZIMC) by the laser engraving processes, which is simple and suitable for large-scale process production. The final ZIMC exhibited a low self-discharge rate of 2.75 mV h−1, a large area-specific capacitance of 83.96 mF cm−2, and maintained an initial capacitance of 86.3% after five self-healing processes. In addition, the ZIMC-powered integrated pressure sensing system enables real-time monitoring of human physiological signals. Combining these prominent performance with the simple device-assembly method makes this microcapacitor highly potential in the next-generation electronics.



中文翻译:

用于多功能锌离子微电容器的层间距调节 MXene/rGO 泡沫

传统的3D多孔结构往往会为了高孔隙率而牺牲密度,这不利于有限空间下的储能。因此,寻求平衡泡沫材料密度和孔隙率的策略是一项挑战。在这项工作中,我们通过肼蒸气诱导还原制备了基于 MXene 的泡沫,可以实现对密度的精确调节(100-360 mg cm -3) 和孔径 (5.08–61.04 μm),同时保持其超过 77.9% 的高孔隙率。它是通过简单地调整原始 MXene/GO 薄膜的氧化官能团浓度来实现的。然后使用层间距调节的3D MXene/rGO泡沫通过激光雕刻工艺构建多功能锌离子微电容器(ZIMC),该方法简单且适合大规模工艺生产。最终的 ZIMC 表现出 2.75 mV h -1的低自放电率,83.96 mF cm -2的大面积比电容,并在五次自愈过程后保持了 86.3% 的初始电容。此外,由 ZIMC 驱动的集成压力传感系统能够实时监测人体生理信号。将这些突出的性能与简单的器件组装方法相结合,使这种微电容器在下一代电子产品中具有很高的潜力。

更新日期:2022-05-27
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