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The detection of Fe (III) and ascorbic acid by fluorescence quenching and recovery of carbon dots prepared from coffee waste
Korean Journal of Chemical Engineering ( IF 2.7 ) Pub Date : 2022-05-21 , DOI: 10.1007/s11814-022-1138-8
Sia Won , Jongsung Kim

Coffee waste-derived carbon dots (C-CDs) that emit blue light were synthesized via hydrothermal process. The synthesized C-CDs have a round shape with average diameter of ∼3.7 nm. The C-CDs show PL emission centered at 450 nm with excitation wavelength at 360 nm. The C-CDs show promising applications as Fe3+ sensors in aqueous solutions by fluorescence quenching. The C-CDs exhibited strong turn-off fluorescence when trace Fe3+ was added to the solution. Furthermore, the C-CDs-Fe3+ can also be used as a turn-on sensor for the detection of ascorbic acid (AA). AA reduces Fe3+ to Fe2+, resulting in the recovery of fluorescence intensity of the quenched C-CDs. Thus, the C-CDs can be used as a rapid and effective dual mode “off-on” fluorescence sensor for Fe3+ and AA. The fluorescence response exhibits a good linear relationship with the concentration of Fe+3 and AA in the range of 0–100 and 0–1 µM, with a limit of detection (LOD) around 4.314 and 0.162 µM, respectively.



中文翻译:

通过荧光猝灭和回收咖啡废料制备的碳点检测 Fe (III) 和抗坏血酸

通过水热法合成了发出蓝光的咖啡废料衍生碳点 (C-CD)。合成的 C-CD 呈圆形,平均直径约为 3.7 nm。C-CD 显示 PL 发射以 450 nm 为中心,激发波长为 360 nm。通过荧光猝灭,C-CDs在水溶液中作为 Fe 3+传感器显示出有前景的应用。当向溶液中添加痕量 Fe 3+时,C-CDs 表现出强烈的关闭荧光。此外,C-CDs-Fe 3+还可用作检测抗坏血酸(AA)的开启传感器。AA 将 Fe 3+还原为 Fe 2+,导致淬灭的 C-CD 的荧光强度恢复。因此,C-CDs 可以作为一种快速有效的双模式“关-开”荧光传感器用于 Fe 3+和 AA。荧光响应在 0-100 和 0-1 µM 范围内与 Fe +3和 AA的浓度呈良好的线性关系,检测限 (LOD) 分别约为 4.314 和 0.162 µM。

更新日期:2022-05-22
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