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Tribological properties of borate ionic liquids with low corrosion grade and excellent thermal stability in 500 N base oil
Lubrication Science ( IF 1.9 ) Pub Date : 2022-04-22 , DOI: 10.1002/ls.1599
Feiming Wang 1 , Xing Gao 2 , Shuliang Zang 3 , Guichun Deng 3 , Shuang Yue 2
Affiliation  

Two borate ionic liquids 1-Butyl-3-(2-methoxy-2-oxoethyl)-imidazole bis(mandelato)-borate [MABIM][BMB]) and 1,3-Dioctylbenzotriazole bis(mandelato)-borate ([DOBI][BMB]) were synthesised and utilised as the lubricating additives. Their corrosion degrees were measured and the results show that [DOBI][BMB] and [MABIM][BMB] exhibit remarkable anti-corrosion properties ([DOBI][BMB]: 1a, [MABIM][BMB]: 1b). The 4-ball machine was employed to evaluate their tribological properties in 500 N base oil. When [DOBI][BMB] and [MABIM][BMB] were added at the concentration of 3.0 wt%, the friction coefficient of 500 N was reduced by 37.5% and 29.5%. It can be concluded from the results of XPS and SEM that a lubricating film containing iron oxide, B2O3 and organic N-containing compounds have formed. And a model is proposed so as to describe the lubricating mechanism.

中文翻译:

低腐蚀等级和优异热稳定性硼酸盐离子液体在500 N基础油中的摩擦学性能

两种硼酸盐离子液体 1-Butyl-3-(2-methoxy-2-oxoethyl)-imidazole bis(mandelato)-borate [MABIM][BMB]) 和 1,3-Dioctylbenzotriazole bis(mandelato)-borate ([DOBI] [BMB]) 被合成并用作润滑添加剂。测量了它们的腐蚀程度,结果表明[DOBI][BMB]和[MABIM][BMB]表现出显着的防腐性能([DOBI][BMB]:1a,[MABIM][BMB]:1b)。使用 4 球机来评估它们在 500 N 基础油中的摩擦学性能。当[DOBI][BMB]和[MABIM][BMB]以3.0 wt%的浓度添加时,500 N的摩擦系数降低了37.5%和29.5%。从 XPS 和 SEM 的结果可以得出结论,含有氧化铁 B 2 O 3的润滑膜并形成有机含氮化合物。并提出了一个模型来描述润滑机理。
更新日期:2022-04-22
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