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Highly Efficient and Selective Hydrogenation of Sugars Catalyzed by Ru-MACHO-BH: Practical Synthesis of Sugar Alcohols
Organic Process Research & Development ( IF 3.4 ) Pub Date : 2022-04-25 , DOI: 10.1021/acs.oprd.2c00047
Hiroki Ishikawa 1 , Taichiro Touge 1 , Wataru Kuriyama 1 , Michio Kida 1 , Kazuhiko Matsumura 1
Affiliation  

A highly efficient synthesis of sugar alcohols was achieved by selective hydrogenation with a homogeneous catalyst. Ru-MACHO-BH, the PNHP-ruthenium catalyst, promoted the hydrogenation with extremely high reactivity and selectivity. The reaction could be applied to various kinds of mono- and disaccharides and has been successfully run on a scale of several tens of grams.

中文翻译:

Ru-MACHO-BH 催化的糖的高效选择性加氢:糖醇的实用合成

通过使用均相催化剂的选择性氢化实现了糖醇的高效合成。PN H P-钌催化剂Ru-MACHO-BH以极高的反应性和选择性促进氢化。该反应可应用于各种单糖和双糖,并已成功在几十克的规模上运行。
更新日期:2022-04-25
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