Physics of Metals and Metallography ( IF 1.2 ) Pub Date : 2022-03-29 , DOI: 10.1134/s0031918x22020107 D. Yu. Vasilenko 1 , A. V. Shitov 1, 2 , D. Yu. Bratushev 1 , K. I. Podkorytov 1 , A. G. Popov 2, 3 , V. S. Gaviko 2, 3 , O. A. Golovnya 2, 3
Magnetic properties and microstructure of (Nd,Dy)–Fe–B magnets with Dy in the range from 0 to 10.3 wt % and oxygen less than 0.26 wt % are studied. High-coercivity magnets with Dy 8 wt % have maximum energy density product (BH)max ≥ 35 MG Oe and coercivity МНс ≥ 30 kOe; their operating temperature can be as high as 180°С. Phase composition and structure of (Nd,Dy)–Fe–B magnets were studied by X-ray diffraction and scanning electron microscopy. In addition to the main (Nd,Dy)2Fe14B phase and (Nd,Dy)2O3 oxide, in triple junctions, there are two (Nd, Dy, Fe, М)Ox phases with fcc structure (symmetry group 225, Fm\(\bar {3}\)m) but with different content of O, Fe, and additional elements M (M = Co, Cu, Ga). It was shown that the total content of (Nd,Dy,Fe,М)Ox oxides grew with the total concentrations of oxygen and dysprosium in magnets.
中文翻译:
Dy小于10 wt%和低氧的高矫顽力(Nd,Dy)-Fe-B磁体的磁滞特性和微观结构
研究了 (Nd,Dy)-Fe-B 磁体的磁性能和微观结构,其中 Dy 在 0 到 10.3 wt% 的范围内,氧在 0.26 wt% 的范围内。Dy 8 wt% 的高矫顽力磁体具有最大能量密度积 ( BH ) max ≥ 35 MG Oe 和矫顽力М Н с ≥ 30 kOe;它们的工作温度可高达 180°С。通过 X 射线衍射和扫描电子显微镜研究了 (Nd,Dy)-Fe-B 磁体的相组成和结构。三结中除了主要的(Nd,Dy) 2 Fe 14 B相和(Nd,Dy) 2 O 3氧化物外,还有两种(Nd,Dy,Fe,М)O x具有 fcc 结构的相(对称组 225,Fm \(\bar {3}\) m)但具有不同含量的 O、Fe 和其他元素 M(M = Co、Cu、Ga)。结果表明,(Nd,Dy,Fe,М)O x氧化物的总含量随着磁体中氧和镝的总浓度而增加。