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Intensified solvent extraction of L-tryptophan in small channels using D2EHPA
Chemical Engineering and Processing: Process Intensification ( IF 4.3 ) Pub Date : 2022-01-21 , DOI: 10.1016/j.cep.2022.108802
Haoyu Wang 1 , Panagiota Angeli 1
Affiliation  

The continuous extraction of an amino acid, L-tryptophan, from aqueous solutions was studied in small channels with diameters of 0.5 and 2 mm. L-tryptophan was separated from nitric acid solutions into hexane using Di(2-ethylhexyl)phosphoric acid (D2EHPA) as extractant. It was found that the plug flow dominated in the flow pattern map at mixture velocities below 0.1 m/s and all organic phase volume fractions in the 0.5 mm channel, while it appeared at mixture velocities below 0.02 m/s and organic phase volume fractions below 60% in the 2 mm channel. During plug flow, the specific interfacial area increased with mixture velocity and acquired maximum values of 4432 and 1456 m2/m3 in the 0.5 and 2 mm channels, respectively. Extraction efficiencies and percentage of up to 95% and 50% were reached in the 0.5 mm channel for residence times less 45 s, while both values were about 5–10% less in the 2 mm channel. Mass transfer coefficients of up to 0.16 and 0.13 s−1 were reached in the 0.5 mm and 2 mm channels, respectively.



中文翻译:

使用 D2EHPA 在小通道中强化溶剂萃取 L-色氨酸

在直径为 0.5 和 2 mm 的小通道中研究了从水溶液中连续提取氨基酸 L-色氨酸。使用二(2-乙基己基)磷酸 (D2EHPA) 作为萃取剂,将 L-色氨酸从硝酸溶液中分离到己烷中。发现在混合速度低于 0.1 m/s 和 0.5 mm 通道中的所有有机相体积分数时,活塞流在流型图中占主导地位,而在混合速度低于 0.02 m/s 和有机相体积分数以下时出现活塞流60% 在 2 mm 通道中。活塞流过程中,比界面面积随混合速度的增加而增加,最大值分别为4432和1456 m 2 /m 3分别在 0.5 和 2 mm 通道中。在 0.5 毫米通道中,停留时间少于 45 秒时,提取效率和百分比分别高达 95% 和 50%,而在 2 毫米通道中,这两个值都减少了约 5-10%。在 0.5 mm 和 2 mm 通道中分别达到了高达 0.16 和 0.13 s -1的传质系数。

更新日期:2022-02-03
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