A kinetic study of the crosslinking reaction between waterborne polymer particles functionalized with aceto acetoxy ethyl methacrylate (AAEMA) and polymer particles functionalized with hexamethylene diamine (HMDA) is presented. Seeded emulsion polymerization is used to synthesize the polymer particles and the crosslinking reaction is followed during the film formation of the two-pack system. The kinetics of reaction with respect to time and temperature are studied using FTIR spectroscopy and rheological measurements, and the effects of crosslinking are also analysed by tensile strength and water absorption test. It is found that room temperature crosslinking occurs, as previously suggested in the literature, but at relatively slow rates. On the other hand, the annealing at 60 °C enhances considerably such crosslinking reactions, leading to fully interparticle crosslinked systems with improved mechanical and chemical resistance properties.

介绍了用甲基丙烯酸乙酰乙酰氧基乙酯 (AAEMA) 功能化的水性聚合物颗粒与用六亚甲基二胺 (HMDA) 功能化的聚合物颗粒之间的交联反应的动力学研究。种子乳液聚合用于合成聚合物颗粒，并在双组分体系的成膜过程中进行交联反应。使用 FTIR 光谱和流变测量研究了相对于时间和温度的反应动力学，并通过拉伸强度和吸水率测试分析了交联的影响。发现发生室温交联，如文献中先前所建议的，但速度相对较慢。另一方面，60°C 的退火显着增强了这种交联反应，