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Significantly improving the mechanical/electrical characteristics of blind-hole Cu filling through crystal coherent modification
Surface & Coatings Technology ( IF 5.4 ) Pub Date : 2022-01-14 , DOI: 10.1016/j.surfcoat.2022.128111
Yu-Ming Lin, Cheng-Yu Lee, Yu-Lien Chen, Chih-Pin Pan, Cheng-En Ho

The crystallographic microstructure between the electroplated Cu fillings and the substrate in a stacked-via structure and its electrical/mechanical characteristics were systematically investigated using a focused ion beam (FIB), electron backscatter diffraction (EBSD), a probe station with an ohmmeter, a quick via pull (QVP) test, and a 3D-optical microscope. A two-stage Cu electrodeposition process with various plating current densities at the early stage (j1 = 0.3, 0.5, 1.0, or 2.0 A/dm2) and a fixed plating current density at the subsequent stage (j2 = 2.0 A/dm2) was utilized to fill a daisy-chain blind-hole (BH) structure. The Cu crystal coherency between electroplated Cu fillings and substrate can be significantly improved with the j1 minimization, which efficiently enhances the electrical/mechanical characteristics of the stacked-via structure. The strong dependence of the Cu crystal coherency on j1 can be ascribed to a slow discharge rate of Cu ions at a low plating current density, allowing the Cu nuclei to laterally extend and epitaxially grow with a crystalline substrate. Therefore, the Cu crystal modification via j1 adjustment can greatly promote the packaging reliabilities of a stacked-via structure.



中文翻译:

通过晶体共格改性显着改善盲孔Cu填充的机械/电气特性

使用聚焦离子束(FIB)、电子背散射衍射 (EBSD)、带有欧姆计的探针台、a快速通过拉力 (QVP) 测试和 3D 光学显微镜。一种两阶段的Cu电沉积工艺,早期电镀电流密度不同( j 1  = 0.3、0.5、1.0或2.0 A/dm 2),后续阶段电镀电流密度固定(j 2  = 2.0 A/分米2) 用于填充菊花链盲孔 (BH) 结构。j 1最小化可以显着改善电镀Cu填充物和基板之间的Cu晶体相干性,这有效地增强了堆叠通孔结构的电/机械特性。Cu 晶体相干性对j 1的强烈依赖性可归因于在低电镀电流密度下 Cu 离子的缓慢放电速率,允许 Cu 核横向延伸并与晶体衬底一起外延生长。因此,通过j 1调整Cu晶体改性可以大大提高堆叠通孔结构的封装可靠性。

更新日期:2022-01-20
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