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Bismuth-210, its parent, and daughter and their use as particle tracers in aquatic systems
Marine Chemistry ( IF 3 ) Pub Date : 2021-12-29 , DOI: 10.1016/j.marchem.2021.104072
James T. Waples 1
Affiliation  

Disequilibrium between 210Pb (t½: 22.3 years) and its granddaughter 210Po (t½: 138.4 days) has been used to infer organic particle removal rates from the surface ocean on a timescale of weeks to months; however, the behavior of the short-lived intermediary daughter 210Bi (t½: 5.01 days) is not well known. Here, timeseries measurements of 210Pb, 210Bi, and 210Po in the Milwaukee Inner Harbor on Lake Michigan showed respective particle distribution (Kd) coefficients of 7.1 (± 0.4) × 105, 9.3 (± 1.7) × 105, and 10.2 (± 0.6) × 105 L kg −1, giving Kd ratios, or fractionation factors (F), of FBi/Pb = 1.3 ± 0.3, FPo/Bi = 1.1 ± 0.2, and FPo/Pb of 1.4 ± 0.1. After a large rain event, total 210Pb, 210Bi, and 210Po activities in the harbor water column decreased over a course of 12 days from 347 to 105 dpm 210Pb m−3, 397 to 88 dpm 210Bi m−3, and 144 to 58 dpm 210Po m−3. This is the first observation of a total 210Bi/210Po activity ratio of <1 in an aquatic system. A 1-D non-steady-state model of nuclide fluxes suggested that 92% of the reduction in 210Bi activity was due to removal from the water column, with the remainder accounted for by net in situ decay. The potential for using 210Bi as a tracer of high and variable particle scavenging rates in lakes and shallow marine systems is supported.



中文翻译:

Bismuth-210、它的母体和子体以及它们在水生系统中作为粒子示踪剂的用途

210 Pb(t½:22.3 年)与其孙女210 Po(t½:138.4 天)之间的不平衡已被用于推断在数周到数月的时间尺度内从表层海洋中去除有机颗粒的速率;然而,短命的中介女儿210 Bi(t½:5.01天)的行为并不为人所知。在这里,密歇根湖密尔沃基内港的210 Pb、210 Bi 和210 Po 的时间序列测量显示各自的粒子分布 ( K d ) 系数为 7.1 (± 0.4) × 10 5、9.3 (± 1.7) × 10 5,和 10.2 (± 0.6) × 10 5  L kg -1,给出F Bi/Pb  = 1.3 ± 0.3、F Po/Bi  = 1.1 ± 0.2 和F Po/Pb 1.4 ± 0.1 的K d比率或分馏因子 ( F ) 。在一场大雨事件之后,港口水体中的210 Pb、210 Bi 和210 Po 的总活性在 12 天的过程中从 347 到 105 dpm 210 Pb m -3、397 到 88 dpm 210 Bi m -3,和 144 至 58 dpm 210 Po m -3。这是第一次观测到总共210 Bi/ 210水生系统中的 Po 活性比 <1。核素通量的一维非稳态模型表明210 Bi 活性降低的 92%是由于从水柱中去除,其余部分由净原位衰减引起。支持使用210 Bi 作为湖泊和浅海系统中高和可变颗粒清除率的示踪剂的潜力。

更新日期:2022-01-05
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