Herein, we have developed a novel B(C6F5)3-catalysed S-H bond insertion of thiophenols and thiols with α-aryl-α-diazoesters under mild condition, furnishing various sulfides in moderate to excellent yield. This method features simple operation, mild conditions, broad substrate scope and easy scale-up, which provide alternative approach for transition-metal catalysed reaction.

中文翻译：

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硼烷催化的苯硫酚和硫醇与 α-芳基-α-重氮酯的 S-H 插入反应

在此，我们开发了一种新型 B(C6F5)3 催化的硫酚和硫醇与 α-芳基-α-重氮酯在温和条件下的 SH 键插入，以中等至优异的产率提供各种硫化物。该方法操作简单、条件温和、底物范围广、易于放大，为过渡金属催化反应提供了替代途径。