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Synthesis of g-carbon nitride-Ag3PO4 nanohybrid using Okra plant extract and their photocatalytic activity for the degradation of fluorescein and crystal violet dyes
Indian Journal of Chemical Technology ( IF 0.5 ) Pub Date : 2021-12-24
R Padmanaban, M Dharmendira Kumar

Development of eco-friendly efficient photo catalyst is an urgent need for waste water treatment in industry. A facile eco-friendly method is established to synthesize hybrid nanocomposite of g-C3N4/Ag3PO4 using Abelmoschus esculentus plant extract and used as highly efficient photo catalyst for degradation of textile toxins and pharmaceutical waste from industrial waste water. The synthesized catalysts have been characterized by FTIR, XRD, SEM, TEM and EDAX analysis. XRD peaks confirm the cubic phase of Ag3PO4, high crystallinity and purity of nanocomposite. SEM studies show nanocomposites with rough surface and irregular morphology. TEM reports confirm the spherical morphology of silver phosphate and it is evenly wrapped on the surface of graphene sheets. EDAX confirms the purity and presence of all elements in composite. Photo catalytic activity of catalyst has been investigated towards degradation of CV and Fluorescein dyes. The superior photo catalytic performance of g-C3N4/Ag3PO4 nanohybrid composite on CV and Fluorescein dye has been observed and compared with recent report of literature. The photo catalytic studies revealed that the synthesized catalyst is efficient and degrade 95% of Fluorescein and CV within 2 hours. Reusability of the catalyst has been evaluated and it reveals stability and recyclability of the catalyst. The mechanism of photo catalytic activity has also been discussed in detail.

中文翻译:

秋葵植物提取物合成g-氮化碳-Ag3PO4纳米杂化物及其光催化降解荧光素和结晶紫染料的活性

开发环保高效的光催化剂是工业废水处理的迫切需要。建立了一种简便的环保方法,使用 Abelmoschus esculentus 植物提取物合成 g-C3N4/Ag3PO4 杂化纳米复合材料,并将其用作高效光催化剂用于降解工业废水中的纺织品毒素和制药废物。通过FTIR、XRD、SEM、TEM和EDAX分析对合成的催化剂进行了表征。XRD 峰证实了 Ag3PO4 的立方相、纳米复合材料的高结晶度和纯度。SEM 研究表明纳米复合材料具有粗糙的表面和不规则的形态。TEM 报告证实了磷酸银的球形形态,它均匀地包裹在石墨烯片的表面。EDAX 确认复合材料中所有元素的纯度和存在。已经研究了催化剂对 CV 和荧光素染料降解的光催化活性。已经观察到 g-C3N4/Ag3PO4 纳米杂化复合材料对 CV 和荧光素染料的优异光催化性能,并与最近的文献报道进行了比较。光催化研究表明,合成的催化剂是有效的,可在 2 小时内降解 95% 的荧光素和 CV。对催化剂的可重复使用性进行了评估,它揭示了催化剂的稳定性和可回收性。还详细讨论了光催化活性的机制。光催化研究表明,合成的催化剂是有效的,可在 2 小时内降解 95% 的荧光素和 CV。对催化剂的可重复使用性进行了评估,它揭示了催化剂的稳定性和可回收性。还详细讨论了光催化活性的机制。光催化研究表明,合成的催化剂是有效的,可在 2 小时内降解 95% 的荧光素和 CV。对催化剂的可重复使用性进行了评估,它揭示了催化剂的稳定性和可回收性。还详细讨论了光催化活性的机制。
更新日期:2021-12-24
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