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Pt3Ni@C Composite Material Designed and Prepared Based on Volcanic Catalytic Curve and Its High-Performance Static Lithium Polysulfide Semiliquid Battery
Nanomaterials ( IF 5.3 ) Pub Date : 2021-12-16 , DOI: 10.3390/nano11123416
Ying Wang 1, 2 , Yao Yao 1 , Yu Chen 3 , Jiyue Hou 1 , Zhicong Ni 1 , Yanjie Wang 1 , Xiuqiong Hu 2 , Yanzhong Sun 3 , Rui Ai 4 , Yulin Xian 1 , Yiyong Zhang 1 , Xue Li 1 , Yingjie Zhang 1 , Jinbao Zhao 3
Affiliation  

There are many challenges for the Static lithium polysulfide semiliquid battery in its commercial application, such as poor stability of the cathode material and further amplification of the lithium polysulfide shuttle effect. Therefore, this manuscript introduced a new type of Pt3 composite material as cathode working electrode based on the principle of volcanic catalytic curve. Through symmetric battery test, CV, polarization curves and impedance test, it was found that Pt3[email protected] composite material had good catalytic activity of lithium polysulfide to improve electrochemical kinetics. When the catholyte was Li2S8 and the charge-discharge voltage range was 1.8~2.6 V, the capacity maintained at approximately 550 mAh g−1, and the coulombic efficiency maintained at approximately 95% after 100 cycles at a current rate of 0.5 mA cm−2. The Pt3[email protected] composite material is a potential cathode material with the specific capacity and long cycling stability of the static lithium polysulfide semiliquid battery.

中文翻译:

基于火山催化曲线设计制备的Pt3Ni@C复合材料及其高性能静态多硫化锂半液态电池

静态多硫化锂半液体电池在其商业应用中面临着诸多挑战,例如正极材料稳定性差、多硫化锂穿梭效应进一步放大等。因此,本手稿基于火山催化曲线原理介绍了一种新型的Pt 3复合材料作为阴极工作电极。通过对称电池测试、CV、极化曲线和阻抗测试,发现Pt 3 [电子邮件保护]复合材料对多硫化锂具有良好的催化活性,可改善电化学动力学。当阴极电解液为Li 2 S 8且充放电电压范围为1.8~2.6 V时,容量保持在约550 mAh g-1,并且在0.5 mA cm -2的电流速率下100次循环后库仑效率保持在大约95% 。Pt 3 [电子邮件保护] 复合材料是一种潜在的正极材料,具有静态多硫化锂半液体电池的比容量和长循环稳定性。
更新日期:2021-12-16
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