The structural and photoluminescence properties of zinc phosphate glasses activated with ${\text{Ag}}_{\text{m}}^{\text{n}+}$ clusters and Eu³⁺ are studied. The addition of Ag⁺ and Eu³⁺ does not significantly modify the glassy structural properties evaluated by X-ray diffraction (XRD) patterns and Raman spectroscopy. The only change observed by Raman spectroscopy, is ascribed to the creation of molecular oxygen. The photoluminescence spectra, recorded under near ultraviolet (NUV) light excitation, display the feature broad band attributed to ${\text{Ag}}_{\text{m}}^{\text{n}+}$ clusters. With the Eu³⁺ addition, Eu³⁺ bands located at 578, 591, 611, 652 and 701 nm, appear on the ${\text{Ag}}_{\text{m}}^{\text{n}+}$ cluster emission, achieving the highest intensity at 0.8 mol% of Eu³⁺. This behavior is accompanied by a gradual reduction of the ${\text{Ag}}_{\text{m}}^{\text{n}+}$ cluster emission. Sinks related to Eu³⁺ absorption on ${\text{Ag}}_{\text{m}}^{\text{n}+}$ cluster emission and shortening of ${\text{Ag}}_{\text{m}}^{\text{n}+}$ cluster: S₁ → S₀ and T₁,T₂ → S₀ emission decays, suggest respectively the existence of radiative and non-radiative energy transfers from ${\text{Ag}}_{\text{m}}^{\text{n}+}$ clusters to Eu³⁺. The Burstein model points out that the non-radiative energy transfer processes are predominantly mediated by electric dipole-dipole interaction for the ${\text{Ag}}_{\text{m}}^{\text{n}+}$ :S₁ → S₀ transition. The emission tonality, estimated from the CIE1931 chromaticity coordinates and correlated color temperature (CCT) can be tuned from the cold white region to the warm white one, with effective quantum yield measurements up to 48%, depending on the excitation wavelength and Eu³⁺ doping content. Emission tonalites out of the white light region (orange-pink, purple-pink and pink) are obtained at higher amounts of Eu³⁺ (0.8 and 1.0 mol%) as well.

磷酸锌玻璃的结构和光致发光特性 ${\text{银}}_{\text{米}}^{\text{n}+}$簇和 Eu ³⁺进行了研究。添加 Ag ⁺和 Eu ³⁺不会显着改变通过 X 射线衍射 (XRD) 图案和拉曼光谱评估的玻璃状结构特性。拉曼光谱观察到的唯一变化归因于分子氧的产生。在近紫外 (NUV) 光激发下记录的光致发光光谱显示特征宽带归因于${\text{银}}_{\text{米}}^{\text{n}+}$集群。与欧盟³⁺另外，铕³⁺频带位于578，591，611，652和701纳米，出现在${\text{银}}_{\text{米}}^{\text{n}+}$簇发射，在 0.8 mol% Eu ^{3+ 时}达到最高强度。这种行为伴随着逐渐减少${\text{银}}_{\text{米}}^{\text{n}+}$簇发射。与 Eu ³⁺吸收有关的汇${\text{银}}_{\text{米}}^{\text{n}+}$ 簇发射和缩短 ${\text{银}}_{\text{米}}^{\text{n}+}$簇：S ₁ → S ₀和T ₁ ,T ₂ → S ₀发射衰减，分别表明存在辐射和非辐射能量转移${\text{银}}_{\text{米}}^{\text{n}+}$簇到 Eu ³⁺。Burstein 模型指出，非辐射能量转移过程主要由电偶极-偶极相互作用介导，${\text{银}}_{\text{米}}^{\text{n}+}$:S ₁ → S ₀转换。根据 CIE1931 色度坐标和相关色温 ( CCT )估计的发射色调可以从冷白区域调整到暖白区域，有效量子产率测量值高达 48%，具体取决于激发波长和 Eu ³⁺兴奋剂含量。在较高量的 Eu ³⁺ (0.8 和 1.0 mol%) 下也获得了白光区域（橙色-粉色、紫色-粉色和粉色）之外的发射色调石。