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Effect of Confinement on Structural and Spectral Characteristics of Composites of CsPbX3 Halide Perovskite Nanoparticles with Zeolites of Faujasite Structure
Theoretical and Experimental Chemistry ( IF 1 ) Pub Date : 2021-11-11 , DOI: 10.1007/s11237-021-09695-1
O. Yu. Posudievsky 1 , N. V. Konoshchuk 1 , O. P. Rozovik 1 , V. G. Koshechko 1 , V. D. Pokhodenko 1 , O. P. Boiko 2 , V. M. Sorokin 3
Affiliation  

CsPbBr3–zIz/Y(X) nanocomposites based on FAU (Y and X) zeolites and halide perovskite nanoparticles (HP NP) with CsPbBr3–zIz composition (z = 0 or 1.8) are prepared. The dependence of HP NP content on the SiO2:Al3O2 ratio in the parent zeolite and the formation of composite nanorods regardless of zeolite type in the case of iodine-containing HP due to the directional growth of CsPbBr1.2I1.8 crystals towards the (110) plane are shown. It is found that CsPbBr3–zIz/Y(X) materials are characterized by a significantly greater lifetime and intensity of photoluminescence in comparison with individual HP due to confinement effect. Highly stable films of CsPbBr3–zIz/Y(X)@Sil (z = 0 or 1.8) nanocomposites in silicone, which are characterized by a significant reduction of the luminescence band width, which is associated with the effect of silicone polymer on halide-ion exchange in HP, are prepared. It is shown that the color rendering index could be increased up to 95, while the partial index R9 could be increased up to 99 at correlated color temperature of ~4500 K when using CsPbBr1.2I1.8/X@Sil in white light emitting diodes.



中文翻译:

限制对 CsPbX3 卤化物钙钛矿纳米颗粒与八面沸石结构复合材料的结构和光谱特性的影响

制备了基于 FAU(Y 和 X)沸石和具有 CsPbBr 3-z I z组成(z = 0 或 1.8)的卤化物钙钛矿纳米粒子 (HP NP) 的CsPbBr 3-z I z /Y(X) 纳米复合材料。HP NP内容的在SiO的依赖性2的Al:3 ö 2比在母体沸石和复合纳米棒的形成而不管沸石型在HP含碘的情况下,由于CsPbBr的定向生长1.21.8晶体朝(110) 平面如图所示。发现 CsPbBr 3–z I z/Y(X) 材料的特点是由于限制效应,与单个 HP 相比,光致发光的寿命和强度明显更长。CsPbBr 3–z I z /Y(X)@Sil (z = 0 or 1.8) 纳米复合材料在有机硅中的高度稳定薄膜,其特点是发光带宽显着降低,这与有机硅聚合物的作用有关在 HP 中进行卤化物离子交换,制备。结果表明,当在白光发光二极管中使用 CsPbBr 1.2 I 1.8 /X@Sil时,显色指数可提高至 95,而部分指数 R 9在~4500 K 的相关色温下可提高至 99 .

更新日期:2021-11-12
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