Monosubstituted 3,3-Difluorocyclopropenes as Bench-Stable Reagents: Scope and Limitations,European Journal of Organic Chemistry

当前位置： X-MOL 学术 › Eur. J. Org. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Monosubstituted 3,3-Difluorocyclopropenes as Bench-Stable Reagents: Scope and Limitations
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-11-08 , DOI: 10.1002/ejoc.202100921
Pavel S. Nosik _{1,

2} , Mykola O. Pashko _{1,

2} , Andrii S. Poturai _{1,

2} , Denys A. Kvasha _{1,

2} , Alexander E. Pashenko _{1,

2,

3} , Alexander B. Rozhenko ₃ , Sergiy Suikov ₃ , Dmitriy M. Volochnyuk _{1,

2,

3} , Sergey V. Ryabukhin _{1,

2,

3} , Yurii L. Yagupolskii ₃

Affiliation

A protocol for the synthesis of gem-difluorocyclopropenes was developed, based on Ruppert-Prakash reagent slow addition. The empiric observations allow to predict whether the compound could be stocked neat, as a solution, or only used after generation in situ.