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A Selective and General Cobalt-Catalyzed Hydroaminomethylation of Olefins to Amines
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2021-11-05 , DOI: 10.1002/anie.202112597
Ji Yang 1 , Fábio G Delolo 1, 2 , Anke Spannenberg 1 , Ralf Jackstell 1 , Matthias Beller 1
Affiliation  

A general and selective synthesis of amines via hydroaminomethylation of olefins in the presence of the specific Co-tert-BuPy-Xantphos catalyst is presented. This novel system is complementary to previously known noble metal catalysts and constitutes one of the most general catalysts for HAM.
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中文翻译:

烯烃选择性和一般钴催化的加氢氨基甲基化成胺

介绍了在特定的 Co- tert -BuPy-Xantphos 催化剂存在下通过烯烃的氢氨基甲基化合成胺的一般选择性合成方法。这种新系统是对以前已知的贵金属催化剂的补充,是最常见的 HAM 催化剂之一。
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更新日期:2022-01-04
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