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Generation of a π-Bonded Isomer of [P4]4− by Aluminyl Reduction of White Phosphorus and its Ammonolysis to PH3
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2021-10-22 , DOI: 10.1002/anie.202112515 Matthew M D Roy 1 , Andreas Heilmann 1 , Mathias A Ellwanger 1 , Simon Aldridge 1
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2021-10-22 , DOI: 10.1002/anie.202112515 Matthew M D Roy 1 , Andreas Heilmann 1 , Mathias A Ellwanger 1 , Simon Aldridge 1
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The reduction of white phosphorus by an aluminum(I) anion is explored. The four-electron reduction product serves as a means of phosphine gas production on exposure to ammonia.
中文翻译:
通过铝基还原白磷及其氨解为 PH3 生成 [P4]4− 的 π 键合异构体
探索了铝 (I) 阴离子对白磷的还原。四电子还原产物用作暴露于氨气时产生磷化氢气体的手段。
更新日期:2021-12-06
中文翻译:
通过铝基还原白磷及其氨解为 PH3 生成 [P4]4− 的 π 键合异构体
探索了铝 (I) 阴离子对白磷的还原。四电子还原产物用作暴露于氨气时产生磷化氢气体的手段。