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Utilization of residual heat to prepare high performance foamed glass-ceramic from blast furnace slag and its reinforce mechanism
Process Safety and Environmental Protection ( IF 7.8 ) Pub Date : 2021-10-19 , DOI: 10.1016/j.psep.2021.10.019
Mingjun Li 1 , Feng Zheng 1 , Yongli Xiao 2 , Yunze Guan 2 , Jiao Wang 1 , Qiang Zhen 1 , Yi Yu 3
Affiliation  

The world's steel production has been closer to two billion tons per year and the blast furnace slag (BFS) is the maximum solid waste during the iron-smelting and steel-making process. To conserve energy and reduce emissions, on-site treatment of BFS to produce high value-added products has become a trend. In this study, the foamed glass-ceramic (FGC) is prepared by using BFS and waste glass as the base materials and the residual heat of pre-heated furnace as the heat source to simulate the high temperature industrial waste heat. The optimal FGC shows a low apparent density of 0.67 ± 0.052 g cm−3, a high porosity of 61.49 ± 1.90%, a good compressive strength of 3.18 ± 0.11 MPa, an excellent strength-to-density ratio of 4.75 MPa cm3 g−1 and a relatively small water absorption ratio of 7.05 ± 0.95%, which could completely satisfy the application requirements in the field of building construction. Combined with the SEM, XRD and TEM results, it can be found that the new formed CaSiO3 crystals plays a bridging role between the glass phase and the ceramic phase pre-existed in the BFS, which could effectively reinforce the compressive strength. This study provides a simple and feasible route to treat solid waste by using industrial waste heat and offers a new idea to solve the similar resources, energy and environmental issues.



中文翻译:

利用余热制备高炉渣高性能泡沫微晶玻璃及其强化机理

世界钢铁产量已接近每年20亿吨,高炉渣(BFS)是炼铁和炼钢过程中最大的固体废物。为节能减排,现场处理BFS生产高附加值产品已成为趋势。本研究以BFS和废玻璃为基材,以预热炉余热为热源模拟高温工业余热制备泡沫微晶玻璃(FGC)。最佳 FGC 表现出 0.67 ± 0.052 g cm -3的低表观密度,61.49 ± 1.90% 的高孔隙率,3.18 ± 0.11 MPa 的良好抗压强度,4.75 MPa cm 3 g的优异强度密度比−17.05±0.95%的较小吸水率,完全可以满足建筑施工领域的应用要求。结合SEM、XRD和TEM结果可以发现,新形成的CaSiO 3晶体在BFS中预先存在的玻璃相和陶瓷相之间起架桥作用,可以有效地增强抗压强度。该研究为利用工业余热处理固体废物提供了一条简单可行的途径,为解决类似的资源、能源和环境问题提供了新思路。

更新日期:2021-10-30
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