A mild visible-light-induced Pd-catalyzed one-pot three-component alkyl-carbamoylation and cyanation of alkenes was developed. This general transformation, which proceeds via the in situ formation of a reactive ketenimine intermediate, allows for a rapid construction of a broad range of valuable amides and nitriles from readily available alkenes, alkyl iodides, and isocyanides. An efficient synthesis of tetrazole and amidine via this approach was also demonstrated.

中文翻译：

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三组分可见光诱导钯催化烯烃的 1,2-烷基氨基甲酰化/氰化

开发了一种温和的可见光诱导的 Pd 催化一锅法三组分烷基氨基甲酰化和氰化烯烃。这种通过原位形成反应性烯酮亚胺中间体进行的一般转化允许从容易获得的烯烃、烷基碘和异氰化物快速构建广泛的有价值的酰胺和腈。还证明了通过这种方法有效合成四唑和脒。