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Effect of 1,2,3- triazole derivative on the dissolution performance of mild steel in 1M HCl medium
Indian Journal of Chemical Technology ( IF 0.5 ) Pub Date : 2021-10-13
K Vijayalakshmi, N Punitha, R Rengamy, J Elangovan

The corrosion mitigation behaviour of 1-benzyl-4-(naphthalen-2-yl)-1H-1,2,3-triazole (BNT) has been explored on mild steel in 1M HCl medium employing chemical and electrochemical techniques. The observed results illustrate that the hindered efficacy was increased as increasing concentration of BNT and with rising temperatures. The electrochemical studies point out that the inspected BNT is a mixed kind inhibitor and the adsorption isotherm discussions proposed the inhibition mechanism obeyed Langmuir isotherm. The kinetic and thermodynamical parameters exposed that the adsorption process is endothermic, spontaneous and the mechanism is both physical and chemical adsorption. Further, the morphological investigations have been carried out by SEM, EDS and AFM techniques. The highest efficiency perceived for BNT is found to be 91.35% and behaved as a proficient inhibitor against mild steel corrosion in the 1M HCl environment.

中文翻译:

1,2,3-三唑衍生物对低碳钢在1M HCl介质中溶解性能的影响

1-benzyl-4-(naphthalen-2-yl)-1H-1,2,3-三唑 (BNT) 的缓蚀行为已在 1M HCl 介质中使用化学和电化学技术在低碳钢上进行了探索。观察到的结果表明,受阻功效随着 BNT 浓度的增加和温度的升高而增加。电化学研究表明所检测的BNT是一种混合型抑制剂,吸附等温线讨论提出了抑制机制服从Langmuir等温线。动力学和热力学参数表明吸附过程是吸热的、自发的,其机理是物理吸附和化学吸附。此外,形态学研究已通过 SEM、EDS 和 AFM 技术进行。发现 BNT 的最高效率为 91。
更新日期:2021-10-13
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