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A Facile Approach to Enhance the UV Blocking Properties of Layered Double Hydroxides and Potential Application in Asphalt
Materials Today Sustainability ( IF 7.8 ) Pub Date : 2021-10-09 , DOI: 10.1016/j.mtsust.2021.100081
E. Xu 1 , P. Chen 2 , G. Wang 1 , K. Li 1 , Y. Lin 1
Affiliation  

Defect-structured ZnaMgbAlc layered double hydroxides (d-ZnaMgbAlc-LDHs) with varying Mg/Zn ratios have been prepared by modifying the surface of ZnaMgbAlc-LDHs through a chemical etching method. The UV blocking properties of d-ZnaMgbAlc-LDHs were significantly improved and d-Zn4Al2-LDH was added into asphalt to explore the potential anti-UV-aging application in asphalt. Research results show that 3 wt.% of d-Zn4Al2-LDH could significantly improve the anti-UV-aging ability of asphalt, resulting from oxygen vacancy defects produced on the surface of d-Zn4Al2-LDH. Specifically, these oxygen defects vacancy can adsorb the free radicals generated during asphalt aging process; therefore, it blocked the fragmentation of macromolecule chain in asphalt and postponed the aging process.



中文翻译:

一种增强层状双氢氧化物紫外线阻挡性能的简便方法及其在沥青中的潜在应用

通过化学蚀刻修饰Zn a Mg b Al c -LDHs的表面,制备了具有不同Mg/Zn比的缺陷结构Zn a Mg b Al c层状双氢氧化物(d-Zn a Mg b Al c -LDHs)方法。d-Zn a Mg b Al c -LDHs的紫外线阻隔性能显着提高,将 d-Zn 4 Al 2 -LDH 添加到沥青中,探索了在沥青中潜在的抗紫外线老化应用。研究结果表明,3wt.%的d-Zn 4 Al 2由于d-Zn 4 Al 2 -LDH表面产生氧空位缺陷,-LDH 可以显着提高沥青的抗紫外线老化能力。具体来说,这些氧缺陷空位可以吸附沥青老化过程中产生的自由基;因此,它阻止了沥青中大分子链的断裂并延缓了老化过程。

更新日期:2021-10-09
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