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Enhanced Photo-Catalytic and Antibacterial Properties of Ni-Doped Cd0.9Zn0.1S Nanostructures
Journal of Inorganic and Organometallic Polymers and Materials ( IF 4 ) Pub Date : 2021-10-07 , DOI: 10.1007/s10904-021-02120-z
S Jothi 1 , Rane Caroleena Ganesh 2 , S Muthukumaran 3 , S K Rathiha 3 , R K Seenivasan 4
Affiliation  

The present work describe the synthesis of Cd0.9Zn0.1S and Cd0.87Zn0.1Ni0.03S nanostructures by chemical co-precipitation method. The XRD profile proved the cubic crystal structure of the samples without any impurity related phases. The reduced size from 63 to 51 Å and the dissimilarities in lattice parameters and micro-strain has been discussed by Ni addition in Cd0.87Zn0.1Ni0.03S structure. The noticed anomalous optical studies and the elevated transmittance at Ni doped sample suggested them for the fabrication of efficient opto-electronic devices. The energy gap reduction during the substitution of Ni = 3% is explained by the generation of extra energy levels associated with defects within the two bands. The release of additional charge carriers, improved optical property, reduced particle size and more defect generation are responsible for the enhanced photo-catalytic performance of Ni doped Cd0.9Zn0.1S. The enhanced anti-bacterial capacity in Cd0.87Zn0.1Ni0.03S is described by the collective response of reduced particle size and higher reactive oxygen species (ROS) like O2⋅−, H2O2 and OH generating capacity.



中文翻译:

Ni掺杂Cd0.9Zn0.1S纳米结构的增强光催化和抗菌性能

本工作描述了通过化学共沉淀法合成 Cd 0.9 Zn 0.1 S 和 Cd 0.87 Zn 0.1 Ni 0.03 S 纳米结构。XRD 曲线证明了样品的立方晶体结构,没有任何杂质相关相。通过在 Cd 0.87 Zn 0.1 Ni 0.03中添加 Ni 讨论了尺寸从 63 减小到 51 Å 以及晶格参数和微应变的差异S 结构。注意到的异常光学研究和 Ni 掺杂样品的透射率升高表明它们可用于制造高效的光电器件。Ni = 3% 替代期间的能隙减小可以通过产生与两个带内的缺陷相关的额外能级来解释。额外电荷载流子的释放、改善的光学性能、减小的粒径和更多的缺陷产生是 Ni 掺杂 Cd 0.9 Zn 0.1 S 的光催化性能增强的原因。 Cd 0.87 Zn 0.1 Ni 0.03 S的抗菌能力增强由减小的粒径和更高的活性氧(ROS)(如 O)的集体响应来描述2 ⋅− , H 2 O 2和 OH 发电量。

更新日期:2021-10-08
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