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Hydrosilylation of Alkenes Using a Hydrosiloxane as a Surrogate for Me2SiH2 and Catalyzed by a Nickel-Pincer Complex
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-09-27 , DOI: 10.1002/ejoc.202101177
Toru Hashimoto 1 , Keisuke Shiota 2 , Toshiya Ishimaru 3 , Yoshitaka Yamaguchi 4
Affiliation  

A nickel-pincer complex bearing a β-aminoketonato-based O,N,P-tridentate ligand was employed for the hydrosilylation of alkenes using 1,1,3,3-tetramethyldisiloxane (TMDS) as a surrogate for Me2SiH2. The reaction of styrene derivatives proceeds smoothly under mild reaction conditions to provide the Markovnikov products in high yields.
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中文翻译:

使用氢硅氧烷作为 Me2SiH2 的替代物并由镍-钳络合物催化的烯烃氢化硅烷化

使用 1,1,3,3-四甲基二硅氧烷 (TMDS) 作为 Me 2 SiH 2的替代物,将带有基于 β-氨基酮基的O , N , P 三齿配体的镍钳配合物用于烯烃的氢化硅烷化。苯乙烯衍生物的反应在温和的反应条件下顺利进行,以高产率提供马尔科夫尼科夫产物。
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更新日期:2021-10-19
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