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Oxidative Dearomatization of Phenols and Polycyclic Aromatics with Hydrogen Peroxide Triggered by Heterogeneous Sulfonic Acids
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-09-27 , DOI: 10.1002/ejoc.202100861 Francesco Pancrazzi 1 , Giovanni Maestri 2 , Raimondo Maggi 1 , Rosanna Viscardi 3
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-09-27 , DOI: 10.1002/ejoc.202100861 Francesco Pancrazzi 1 , Giovanni Maestri 2 , Raimondo Maggi 1 , Rosanna Viscardi 3
Affiliation
Suitable heterogeneous sulfonic acid derivatives ensure the smooth dearomatization of phenols and bare naphthalenes under mild conditions. The method uses hydrogen peroxide which is a clean oxidant, offering a convenient metal-free tool to access families of quinones derivatives in good yields and with low catalyst loadings.
中文翻译:
多相磺酸引发过氧化氢对苯酚和多环芳烃的氧化脱芳构化
合适的多相磺酸衍生物确保酚类和裸萘在温和条件下顺利脱芳构化。该方法使用过氧化氢,它是一种清洁的氧化剂,提供了一种方便的无金属工具,可以以良好的收率和低催化剂负载量获得醌类衍生物。
更新日期:2021-10-19
中文翻译:
多相磺酸引发过氧化氢对苯酚和多环芳烃的氧化脱芳构化
合适的多相磺酸衍生物确保酚类和裸萘在温和条件下顺利脱芳构化。该方法使用过氧化氢,它是一种清洁的氧化剂,提供了一种方便的无金属工具,可以以良好的收率和低催化剂负载量获得醌类衍生物。